PPE (Polyphenylene Ether)
Description

A High-Performance Engineering Thermoplastic

Polyphenylene Ether (PPE), also known as Polyphenylene Oxide (PPO), is a high-performance, rigid amorphous engineering thermoplastic. PPE offers excellent heat resistance, dimensional stability, mechanical strength, and electrical insulation properties. With low moisture absorption, good water resistance, and chemical resistance, PPE is suitable for various high-performance industrial applications.

Enhanced Performance and Processability of Modified PPE

Due to its high melt viscosity, pure PPE has relatively poor melt flowability and presents challenges during processing and molding. Therefore, commercial PPE materials are commonly supplied in modified forms, known as Modified PPE (mPPE) or Modified PPO (mPPO). Through blending with other engineering plastics and reinforcing materials, such as PS and glass fiber, mPPE achieves improved processability and enhanced overall performance. Compared with pure PPE, modified grades provide better molding characteristics and stress crack resistance while maintaining excellent rigidity, heat resistance, dimensional stability, and electrical properties. In addition, mPPE exhibits good creep resistance, water vapor resistance, and low dielectric loss, making it suitable for applications requiring long-term reliability and stable performance.

Wide-Ranging Applications of Modified PPE

Thanks to its outstanding balance of mechanical, thermal, and electrical properties, mPPE is widely used in photovoltaic systems, new energy vehicles, water treatment equipment, electrical enclosures, electronic components, communication devices, industrial parts, and semiconductor-related applications. Prochase supplies a wide range of mPPE grades to meet different application requirements, providing suitable material solutions for various industries.

Features
  • Outstanding Electrical Properties: Outstanding electrical insulation performance with low dielectric constant and low dielectric loss. Its stable electrical properties over a wide range of temperature and humidity conditions make it suitable for electronic and electrical applications.
  • Excellent Dimensional Stability & Low Moisture Absorption: With extremely low moisture absorption, mPPE maintains excellent dimensional stability and reliable performance under humid, thermal, and long-term operating conditions.
  • High Heat Resistance: mPPE offers excellent thermal stability and maintains mechanical performance under elevated temperature conditions, making it suitable for demanding applications.
  • Excellent Mechanical Strength & Creep Resistance: The rigid molecular structure of PPE provides high stiffness, good mechanical strength, and excellent resistance to creep deformation, ensuring long-term reliability of components.
  • Good Chemical Resistance & Flame Resistance: mPPE provides good resistance to water, steam, acids, bases, and salt solutions. F
Applications
Category Key Applications
Electrical & Electronics Electrical housings, connectors, switches, relays, coil bobbins, insulation components, electronic components
Automotive & New Energy Battery components, electrical systems, sensors, connectors, interior components, structural parts
Water Management & Fluid Handling Pump casings, impellers, valves, water meter shells, fluid control components, water treatment equipment
Semiconductor & Industrial Equipment Semiconductor equipment components, precision parts, chemical-resistant components, machine housings
Home Appliances & Consumer Electronics Appliance components, TV components, printer parts, office equipment housings, structural components
Industrial Applications Mechanical parts, structural components, customized engineering applications
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Technical Data

Polyphenylene Oxide Modified

Item Property Test Method Unit Value
Physical Density ASTM D792 g/cm3 1.08
Water Absorption ASTM D570 % 0.07
Rockwell Hardness ASTM D785 R scale 119
 
Mechanical Tensile Modulus ASTM D638 psi 3.5 × 105
Tensile Strength ASTM D638 psi 9,600
Tensile Elongation ASTM D638 % 1.0 – 2.0
Flexural Modulus ASTM D790 psi 3.6 × 105
Flexural Strength ASTM D790 psi 13,500
Izod Impact ASTM D256 ft-lb/in 5.0
 
Thermal Vicat Softening Point ASTM D648 °C/°F 154 / 310
Heat Deflection Temperature at 264 psi ASTM D648 °C/°F 129 / 265
Coefficient of Linear Thermal Expansion ASTM D696 in./in./°F 3.3×10-5
Flammability ASTM D635 - HB
 
Electrical Electrical Volume Resistivity ASTM D257 Ω-cm 1017
Surface Resistivity ASTM D257 Ω / sq 2.0×1016
Dielectric Constant ASTM D150 60 Hz 2.7
Dissipation Factor ASTM D150 60 Hz 0.0007
Dielectric Strength ASTM D149 V/mm 19,700